Photokinetics of the infrared laser radiation effect on mixture of the CO2-N2-H2O atmospheric gases: Advanced model

Authors: A.V. Glushkov, , O.Yu.Khetselius, Yu.Ya.Bunyakova, G.P.Prepelitsa, O.N. Grushevskii, V.V. Buyadzhi

Year: 2014

Issue: 18

Pages: 193-197


Within the refined 3-modal model of kinetic processes there is examined a photokinetics of the energy exchange in a mixture of CO2-N2-H2O atmospheric gases while passing powerful laser CO2 radiation  through an atmosphere.

Tags: laser field; mixture of gases; photokinetics; refined 3-model model


  1.  Zuev V.E., Zemlyanov A.A., Kopytin Y.D. Nonlinear Optics of Atmosphere.- L.:Hidrometeoizd., 1991.-256p.
  2.  Zuev V.E., Zemlyanov A.A., Kopytin Y.D., Kuzikovsky А.V. Powerful laser radiation in an atmospheric aerosol.-Novosybirsk, 1984.-224p.
  3.  Bagratashvili V.N., Letokhov V.S., Makarov A.A., Ryabov E.A. Multi-Photon Processes in Molecules in Infrared laser field.-M.: Nauka,1991-180p.
  4.  Bates N.R., Merlivat L. The influence of short-term wind variability on air-sea CO2 exchange // Geophysical Research Letters. – 2001. – Vol. 28. – No. 17. – P. 3281-3284.
  5.  Gordiets B.F., Osipov A.I., Khokhlov R.V. About cooling the gas under powerful CO2 laser radiation passing in atmosphere// J.Techn.Phys.-1974.-Vol.14.-P.1063-1069.
  6.  Glushkov A.V., Khokhlov V.N., Prepelitsa G.P., Tsenenko I.A. Temporal variability of the atmosphere ozone content: Effect of North-Atlantic oscillation// Optics of atmosphere and ocean.-2004.-Vol.14,N7.-p.219-223.
  7. Stephens B.B., Keeling R.F., Heimann M., Six K.D., Murnane R., Caldeira K. Testing global ocean carbon cycle models using measurements of atmospheric O2 and CO2 concentration // Global Biogeochemical Cycles.–1998.–Vol. 12.–No. 2.–P. 213-230.
  8. Glushkov A.V., Ambrosov S.V., Malinovskaya S.V. etal, Spectroscopy of carbon dioxide: Oscillator strengths and energies of transitions in spectra of СО2 // Optics and Spectroscopy.- 1996.- Т.80,N1.-С.60-65.
  9. Turin A.V., Prepelitsa G.P., Kozlovskaya V.P., Kinetics of energy and heat exchange in mixture CO2-N2-H20 of atmospheric gases interacting with IR laser radiation: Precise 3-mode kinetical model// Phys. Aerodisp. Syst.-2003.-N40.-P.123-128.
  10.  Glushkov A.V., Malinovskaya S.V.,Shpinareva I.M., Kozlovskaya V.P., Gura V.I. Quantum stochastic modelling energy transfer and effect of rotational and V-T relaxation on multiphoton excitation and dissociation for CF3Br molecules// Int. Journ.Quant.Chem.-2005.-Vol.104,N(5).-P.512-520.
  11.  Prepelitsa G.P., Bunyakova Yu., Korban V.Kh., Seredenko S.S., Karpenko A. Photokinetics of the IR laser radiation effect on mixture of the CO2-N2-H20 gases: advanced atmospheric model // Photoelectronics.- 2009.-N18.-P.36-39.
  12.  Glushkov A.V., Khetselius O.Yu., Svinarenko A.A., Mischenko E.V., Florko T.A. Optimized perturbation theory scheme for calculating the interatomic potentials and hyperfine lines shift for heavy atoms in the buffer inert gas//Int. Journ. of Quantum Chemistry.-2009.-Vol.109,N14.-P.3325-3329.
  13.  Glushkov A.V., Khetselius O.Yu., Svinarenko A.A., Prepelitsa G.P. , Shakhman A.N. Spectroscopy of cooperative laser-electron nuclear processes in diatomic and multiatomic molecules // Spectral Lines Shape (AIP, USA).-2010.-Vol.16.-P.269-273.
  14.  Fedchuk A.P., Glushkov A.V., Lepikh Ya.I., Svinarenko A.A., Loboda A.V., Lopatkin Yu.M. The Green’s functions and density functional approach to vibrational structure in the photoelectron spectra of carbon oxide molecule//Photoelectr.-2010.-N19.-P.115-120.
  15.  Khetselius O.Yu., Florko T.A., Svinarenko A.A., Tkach T.B. Radiative and collisional spectroscopy of hyperfine lines of the Li-like heavy ions and Tl atom in an atmosphere of inert gas// Physica Scripta (IOP, London).-2013.- Vol.T153-P.01437 (5p.).
  16.  Wang, C. ENSO, climate variability, and the Walker and Hadley circulations. The Hadley Circulation: Present, Past, and Future (Eds H. F. Diaz and R. S. Bradley). Springer (2004).
  17.  Boer G.J., Sargent N.E. Vertically integrated budgets of mass and energy for the globe // J. Atmos. Sci. – 1985. – Vol. 42. – P. 1592-1613.
  18.  Trenberth K.E., Stepaniak D.P., Caron J.M. Interannual variations in the atmospheric heat budget // J. Geophys. Res. – 2002. – Vol. 107. – P. 4-1 – 4-15.
  19.  Fyfe J.C., Boer G.J., Flato G.M. Predictable winter climate in the North Atlantic sector during the 1997–1999 ENSO cycle // Geophysical Research Letters. – 1999. – Vol. 26. – No. 21. – P. 1601-1604.
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